Association des Constructeurs Europeéns d’Automobiles.
Successor organisation of CCMC and CLCA. Represents the European automobile industry in respect of operating supplies (fuel and lubricants). The specifications originally issued by the CCMC (organisation that proceeded the ACEA) are still valid: G 4, G 5, D 4, D 5 and PD 2. (See CCMC.)
ACTIVE INGREDIENTS (ADDITIVES)
Additives which are added to mineral oils, mineral oil products and synthetic oils
as substances soluble in oil. As a result of a chemical and/or physical effect, they change or improve the characteristics of lubricants, fuels, heating oils, etc. in respect of characteristics such as oxidation stability, flow characteristics and anti-knock properties.
Oil-soluble substances added to lubricants to obtain and optimise certain characteristics. For example, through their chemical or physical action they influence: viscosity temperature characteristics, pour point, flow characteristics, oxidation stability, foam formation, detergent action etc.
Undesired chemical change in mineral and synthetic products during use and storage.
These are used to assess the length of time for which lubricating oil can be used for the specific application.
American Gear Manufacturers Association. Lubrication recommendations for open and closed industrial gear units. Classification into nine viscosity grades.
AIR FILTER OILS
Odour-free and ageing-resistant oils for cleaning the air intake (20 – 100 mm2/s40). White oils must be used for special systems.
ALUMINIUM COMPLEX LUBRICATING GREASES
are highly resistant to water, are easy to handle and hardly exude any oil. Have a high dropping point (to over 230°C) and good high-pressure characteristics. Application temperatures up to approx. 160°C.
It specifies the performance (resistance) of a spark-ignition engine in respect of detonation during combustion in the engine: DIN 51 756 P 1 to P 6, RON (Research Octane Number), MON (Motor Octane Number), FON (Front Octane Number) and ROON (Road Octane Number).
Active ingredients which aim to reduce wear in mixed friction areas; a distinction is made between:
a) Mild-acting additives such as fatty acids, fatty oils (highly polar, surface-active substances), metal dithiophosphates, etc.
b) High-pressure additives made of lead, sulphur, chlorine, phosphorous connections, etc.
c) Solid lubricants such as graphite, molybdenum disulphide, etc. – see EP additives.
Coolant, which in its concentrated form contains approx. 90% ethylene glycol and propylene glycol, inhibitors, additives, colorants and a very small amount of water. Specifications for coolant are what are termed company specifications stipulated by the individual vehicle manufacturers. They also specify the mixing ratios.
Chemical additives that slow down the ageing of oil considerably.
The American Petroleum Institute classifies the requirements of various American engine manufacturers into a system of service categories (classifications). These differentiate between gear oils for passenger cars, engine oils for spark-ignition engines and diesel engine oils.
The American Petroleum Institute uses the following service categories:
API classification for engine oil (commercial categories)
Engine oils for diesel engines are classified into CA to CG categories. For these lubricant categories, too, the same evolution can be seen as for the service classes. Today we are particularly interested in CD categories for heavy duty diesel engines with and without turbocharging, CE for very heavy duty and high-speed diesel engines with and without turbocharging and sharply fluctuating loads. After 1994 CD was superseded by CF. The newly created CF-2 for two-stroke diesel engines and the CF-4 specification, which supersedes CE and defines additional values such as those that relate to volatility loss and piston cleanliness, are of interest. Since June 1994 the CG specification has also included emissions limits for the latest generation of engines.
API classification for engine oil (service categories)
These specifications are very common.
Engine oils for spark-ignition (petrol) engines are classified in the categories SA to SH. SA generation products hardly used to contain any additives (non-compounded). The subsequent SB and SC generations contained mild compounds with active substances to prevent carbonisation, cold sludge, ageing, corrosion and wear. In 1968 the SD category satisfied the increased demands of the vehicle manufacturers. The next generations of SE, SF and SG engine oils for the toughest requirements met the requirements for more powerful engines and new traffic situations (stop-and-go traffic) in the 1970s and 1980s. Since 1993 the SH specification has been used. This also specifies the volatility loss (NOACK), filterability, foaming behaviour and flash point.
API classification for passenger car gear lubricants
Gear oils rated GL 1 to GL 5. A product with the required rating is used depending on the application, design of the gear mechanism and the load. For instance, GL1 is a non-compounded oil for gear trains and worm gears as well as helically toothed and spiral-cut final drives with minimal loads. Nowadays the greatest demand in the market is for GL 4 and GL 5 specifications. The GL 5 rating covers gear oils for highly loaded hypoid axle drives and, in some cases manual and special gearboxes as well. GL 6 oils for very highly loaded final drives have now been withdrawn.
Hydrocarbon compounds with cyclic molecular structures. They produce viscosity temperature characteristics (see VI) in lubricants and have a bad effect on resistance to oxidation. Added to fuel for spark-ignition engines to prevent combustion knock. The percentages added are increasingly being limited on account of their carcinogenic effect.
Mineral deposits that remain after lubricants have been burnt, in the form of oxides (oxide ash) or sulphate (sulphate ash after sulphuric acid has been added).
A mixture made of bitumen and mineral building materials (sand etc.).
AUTOMATIC TRANSMISSION FLUID (ATF)
ATFs are special lubricants with specific and high requirements for automatic transmissions. What are required are very good temperature characteristics and shear stability, high oxidation stability and excellent anti-foaming properties and air release characteristics. The specifications currently used are very extensive. Here are the most recent ones: GM Dexron III, FORD Mercon, MB 236.8, etc.
Aviation lubricant which is adapted to the special requirements of the aircraft engine through its processing and composition. Mainly synthetic oils.
Coolants mixed with water (e.g. emulsions) provide good nutrients for bacteria, yeasts and fungus. Bactericides protect the emulsion from infestation by bacteria, which may also manifest itself in the form of unpleasant odours, corrosion of workpieces, a reduction in the pH value, etc.
BARIUM-COMPLEX LUBRICATING GREASES
Lubricating greases with good high-pressure characteristics and high resistance to water.
Lubricants made of barium soaps and mineral or synthetic oils. Highly water repellent, good shear stability, but generally have poor low-temperature characteristics.
The barrel is an international capacity measure which has been used in the mineral oil sector since the start of oil production. Production output and prices are set in barrels or dollars per barrel. 1 Barrel = 42 US gallons = 159 Litres.
Important content of mineral and synthetic oils in mixed or compounded lubricants such as engine and gear oils or in products such as lubricating greases. The type and quantity of base oils are decisive for characteristics such as viscosity temperature characteristics, resistance to oxidation, response to additives, etc.
Mixing and adding of mineral and synthetic oil products in heatable mixing vessels with agitators (MOTOREX mixer: 0.3 – 20 m3). The temperature must be selected so that all parts to be mixed are distributed uniformly and yet still no undesired reactions occur.
Minerals (e.g. aluminum silicate, montmorillonite, etc.), which act as thickeners for the manufacture of temperature-resistant lubricants with good refrigerating characteristics.
These are petroleum oil hydrocarbons in the boiling range of approx. 25°C to approx. 215°C. They are divided into:
A. Raw gasoline (naphtha)
Feedstocks for petrochemicals and intermediate products such as ethylenes, propylenes, etc.
B. Special and test benzin
For various applications such as for cleaning agents, solvents, benzin for chemical preparatory and analytical purposes, etc.
C. Engine benzin
Fuel (chain and cyclic hydrocarbon mixtures) produced for spark-ignition engines using special refining methods, with the familiar qualities available at service stations.
D. Aircraft turbine fuels
For jet engines (jets, turbines), also called kerosene.
E. Aviation fuel
For aircraft with piston engines (sports aircraft)
Cyclic hydrocarbon produced as a distillation product when coking bituminous coal or also during cracking processes (see cracking process).
BIOLOGICALLY DEGRADABLE LUBRICANT
This means the biochemical decomposition of organic chemical compounds accelerated by microorganisms. Microorganisms such as bacteria, fungi, protozoa, etc. bring about biological degradation through what is termed bio-oxidation. This occurs in several stages, producing CO2, water, protein cell material and multiplication of micro-organisms. At the present time, there are three groups of lubricants that can be broken down quickly biologically: Polyethylene glycol, vegetable oils and certain synthetic esters. They serve as a basis for two-stroke, chain, release, lubricating and hydraulic oils and greases, etc.
It is produced during the environmentally compatible processing of crude oils (residue of vacuum distillation). Dark-coloured, semi-solid, meltable, high-molecular hydrocarbon mixtures. Bitumen is used in asphalt and as an insulating material, etc.
BLANK HARDENING OILS
High-quality refined products that are highly resistant to ageing, non-compounded or inhibited, which do not deposit any residues on the workpiece.
The lubricating oil contained in lubricating grease is separated from the soap skeleton. Bleeding of grease at the lubricating point may mean that the grease is not stable enough in use and/or is not temperature-resistant.
Refining mineral oil products by means of additives, in accordance with a formula. The delicate mixing process is undertaken in a tank or vessel as "batch blending" or in computer-controlling mixing systems over 2 to 5 hours at temperatures of between 60 and 110 °C.
Rich oils blown with hot air at temperatures of approx. 80 to 120°C, thus enlarging the molecules and thickening the oil.
Occurs if the lubricating film is broken or destroyed during friction. Two mating surfaces of materials make contact as a result of conditions that promote friction such as pressure or speed. Boundary friction cannot be avoided before a load-carrying lubricating film is formed during start-up and shutdown and when the direction of rotation changes.
Lubricating oils for running in new machines, engines, etc. so that roughness points can be smoothed or evened out via chemical/physical processes in as controlled a manner as possible, so that a larger percentage of contact area can be achieved for the surfaces that slide against each other.
Highly viscous, refined light residue of lubricating oil. Possesses a very good lubricating action and is a mixing component in lubricating oils.
Lowest temperature, referred to a certain pressure, at which the vapours of a uniformly warmed fluid continue to burn for a further five seconds after ignition by a flame: DIN ISO 2592
a) Oil for removing salt deposited on workpieces made of burnishing salt solutions
b) Oil for blackening the surface of steel parts
Hydrocarbon C4H10 that is a gas at a normal temperature: DIN 51 622
Highly viscous mineral oils for impregnating insulating paper for high-voltage cables; sometimes mixed with waxes, bitumen, resins and pitch (filling compound).
a) Substances which cause a chemical reaction (acceleration, retardation, direction) in other substances without the catalyst itself changing. In the petroleum industry, generally solid catalysts are used, e.g. cobalt, molybdenum, platinum, nickel, etc.
b) Catalytic converters for combustion engines: when used in conjunction with a Lamda sensor and a control unit, this changes harmful emissions in exhaust gas (hydrocarbons CH, nitrous oxide NO and carbon monoxide CO) into non-polluting emissions (water vapour H2O, carbon dioxide CO2 and nitrogen N).
Cavities can be formed if, as a result of flow or vibration, the vacuum in a unit falls below the vapour pressure of the fluid used. When the vacuum drops, the microscopic bubbles that have formed suddenly liquefy (implode): This causes the destruction of metals, bearings, gear wheels, etc.
Unit of dynamic viscosity.
(1 cP = 1 mPa s)
Unit of cinematic viscosity.
(1 cSt = 1 mm2/s)
Microcrystalline waxes in soft, plastic, solid and hard consistencies, with colours ranging from white to yellow; the paraffin content depends on how it is to be used.
CETANE NUMBER (CN)
Measure to indicate the ignition quality of diesel fuel. It specifies the percentage by volume of cetane contained in a blend alpha methylnaphthalene at which the same ignition retardation is established as for the diesel fuel to be tested: DIN 51 773
Is the temperature at which - under specified test conditions - the separation of paraffin crystals causes a bright fluid product to become cloudy. To determine the cloud point: DIN ISO 3015
Residues are produced during vacuum distillation and in various crack systems that are heavier than heavy heating oil. Undesirable substances such as metal compounds, sulphur, nitrogen compounds, etc. are removed during pre-treatment in the coker before further processing.
This forms in the crankcase of engines that run at low loads and at low operating temperatures and is caused by combustion products and condensed water. Cold sludge can cause premature engine wear and engine damage.
Extremely small gelatinous particle which is distributed as very fine particles in another substance (soap solutions, oil emulsions, suspensions, etc.)
Lubricating oils or greases which contain one or several active ingredients (additives) to improve special characteristics (see active ingredients), e.g. ageing stability, viscosity temperature characteristics, cleaning and dispersive effect (detergent, dispersive agent), load-bearing capacity or prevention of wear, corrosion protection, etc.)
Mixtures of mineral oils and greases. The type and quantity of blended grease and oil depends on the application for the compounded oil (cutting oils, marine oils, cylinder oils, lubricating oils, etc.).
COMPRESSOR LUBRICATING OILS
Compressor lubricating oils, used in air compressors with oil-lubricated pressure chambers without injection cooling. These lubricating oils can also be used in air vacuum pumps, which deliver pressure against a high atmospheric pressure. The lubricating oils are classified into different classes, depending on the application and the final compressor temperatures: DIN 51 506.
CONCRETE RELEASE AGENT
Also called formwork or mould oils. Application in the construction industry as a layer to separate wood or steel formwork. Use as oil in oil-in-water or water-in-oil emulsion.
Dimension for the solidity or fluidity of lubricating greases; consistency classification of lubricating greases (NLGI classes) in accordance with: DIN 51 818. Determination of cone penetration: DIN ISO 2137; DIN 51 804 P 2 (see penetration).
Lubricants to cool and lubricate when cutting and, in some cases, shaping materials; cutting oils, metalworking fluids, water-miscible and water-mixed coolants, oil-in-water and water-in-oil emulsions, etc. Terms: DIN 51 385; Checking corrosion protection characteristics: DIN 51 360 P ?; emulsifiability resistance: DIN 51 367; determination of the part removable with acid: DIN 51 368, pH value: DIN 51 369.
Oils to dissipate heat in very different systems, e.g. rectifiers, etc.
These are fractions with closely limited vacuum distillation boiling ranges for lubricating oils for which certain base oil quality requirements are set.
This is a special mould oil for creating cores in a metal foundry.
Extremely alkaline metal sulphonates and phenates. They prevent the creation of rust on metal surfaces through the formation of surface films (absorption of polar surface-active substances which have a chemical and physical effect and thus prevent water and oxygen from penetrating to the surface of the metal) and/or neutralisation of acids.
CORROSION-PROTECTING OILS AND GREASES
Oils and greases to protect metal surfaces that are sensitive to corrosion against attack by moisture and atmospheric oxygen.
Cracking is the name given to the process that breaks the molecular bonds of hydrocarbons. Cracking is a process used in the petrochemicals industry to break down large hydrocarbon molecules by inducing internal oscillations through thermal and/or catalytic methods to produce new, smaller molecules of hydrocarbons.
Unleaded, degassed, desalinated petroleum from which water and solid contaminants have been removed.
Lubricating grease to lubricate plain bearings and sliding surfaces that are only subject to light loads at temperatures up to 60°C.
Coolants that cannot be mixed with water (metal processing oils) for operations to cut metal. The task of these oils is to lubricate, dissipate heat and remove swarf. Depending on the application, S, Cl, Pb,
Sn, P, etc. are added. However, for a long time the cutting oils used have very largely been free of chlorine and heavy metals.
Are used for hardening, tempering and reheating steel. A distinction is made between tempering oils, hot-bath hardening oils, high-performance hardening oils, bright-annealing oils (for shiny surfaces), hardening oils that can be washed off and emulsifiable hardening oils, which can be used depending on the steel type, cooling capacity, hardening process and material requirements.
HEAT DISSIPATING OIL
Mineral or synthetic oil that is temperature- and oxidation resistant with a high flash point, which can be used as a heat exchanging medium for cooling or heating. DIN 51522.
Are liquid fuels which must be suitable to be burnt in different ways. EL heating fuel is an extra light fuel made of hydrocarbons (middle distillate). They may contain hydrocarbon-soluble active ingredients: DIN 51 603 P 1.
HEAVY-DUTY ENGINE OIL (HD OIL)
Engine oil that is specifically adapted to the tough requirements for diesel and spark-ignition engines by adding active substances.
Passenger car engines or gear oils which, compared with conventional - e.g. SAE 15W/40 engine oils or SAE 80W/90 gear oils - save fuel when they operate thanks to reduced friction, ensure better starting of engines at low temperatures and supply oil lubrication quickly to the various units. Called Fuel Economy Oils and Fuel Efficient Oils (FEO). The reduction in friction can be achieved by lowering the viscosity, using certain synthetic base oils and/or adding active ingredients that reduce friction. High-lubricity engine oil requirements in accordance with CCMC specifications G 5, Ilsac GF-1 (API SG or SH with EC II).
Lubricating oils and greases with high-pressure additives (Extreme Pressure = EP), which prevent greater wear and seizing where boundary friction is present; the active substances are polar additives, and chlorine, sulphur and phosphorus, etc. in loose compounds; for instance, metal salt layers are created during friction; these prevent direct contact between metals. (See EP lubricants.)
These are hydraulic oils (pressure fluids) made of mineral oils with active substances to enhance corrosion protection and resistance to ageing: DIN 51 524 P 1.
These are hydraulic oils (pressure fluids) made of mineral oils with active ingredients to increase corrosion protection and resistance to ageing, as well as reducing fretting damage in mixed friction areas. DIN 51 524 P 2, VDMA 24 318.
Are hydraulic oils with detergent additives.
Thin-bodied cutting oil for honing processes when working metal; viscosity approx. 6 to 10 mm2/s at 20°C. Crucial factors are: honing type, speed, material, honing stones, etc.
HOT BEARING LUBRICATING GREASES
The more modern designation is high-temperature grease; lithium greases can be used for continuous temperatures up to approx. 130°C and peak temperatures of up to approx. 140°C; bentonite greases can be used for continuous temperatures up to 160°C and special MoS2, silicone and synthetic greases are suitable up to max. 260°C.
L, T and M heating oils are liquid fuels made of petroleum, shale oil, and bituminous-coal or lignite tars: DIN 51 603 P 2.
S heating oil is a heavy fuel made from processing mineral oil and mineral oil products: DIN 51 603 P 3.
ZT and C heating oils are liquid fuels produced by processing shale oil, aromatic fractions, and bituminous-coal and lignite tars: DIN E 51 603 P 4.
SA heating oil is a heavy low-sulphur fuel made from processing mineral oil and mineral oil products.
These are hydraulic oils (pressure fluids) made of mineral oils with active ingredients to increase corrosion protection and resistance to ageing; they also reduce fretting damage in mixed friction areas and improve the viscosity temperature characteristics. DIN 51 524 P 3.
Ageing-resistant, thin-bodied, non-foaming, highly refined pressure fluids made of mineral oil and/or synthetic oil with a low pour point for use in hydraulic systems, primarily with hydrostatic drives; they may also be used in hydraulic systems with hydrodynamic drives providing that they comply with the requirements of these drives.
This exists if, when moving, the sliding surfaces are completely separated by a lubricating film.
This is the term used for the process to add hydrogen to a chemical compound, causing energy to be released, e.g. adding hydrogen to carbon or hydrocarbon compounds, improving middle distillates, lubricating oils, etc.; destructive hydrogenation is the process that breaks up heavy oils into lighter hydrocarbon compounds by adding hydrogen.
HYPOID GEAR OILS
High-pressure lubricating oils with EP additives to improve the lubricating performance and to avoid the likelihood of corrosion; mainly used for final drives in vehicles with spiral-tooth and hypoid bevel-gear drives.
Purified wool fat from sheep used as an ointment base for cosmetics, to grease textiles and leather goods and to protect against rust.
Boiling fraction of petrol up to approx. 100°C.
a) Customs definition for low-boiling mineral oils (petroleum, benzin, test benzin).
b) Tar oils with a specific weight of approx. 0.930 kg/l.
LIME SOAP LUBRICATING GREASE
Lubricating greases containing calcium and therefore highly water repellent are suitable as grease for crank handles, roller grease, hydraulic lubricating grease, axle bearing grease from –20°C to 70°C.
LS active ingredients are, for instance, used in hypoid gearbox oils for lockable differentials and ATFs (see friction modifiers).
LITHIUM LUBRICATING GREASES
Lubricating greases are produced by saponification of oils with lithium 12 hydroxystearate; they have good water resistance and can be used over a large temperature range; they are generally compounded with AO, AC and EP active ingredients and are often called multi-purpose greases. High dropping point, application temperature – 25° to 130°C.
For mineral oil products - see cloud point, flow properties, flocculation point and pour point.
Have the task of reducing friction and wear when two points, lines or surfaces move on top of each other and have sliding or rolling contact. A distinction is made between fluid, plastic solid, solid and gaseous lubricants.
Indicates the load-bearing capacity of the film produced by a lubricant. It must always be linked to actual conditions such as the type of friction, the friction situation, mating surfaces of materials where friction occurs, lubrication of the contact surfaces, speed and temperature.
They are consistent mixtures of thickeners and oils. A distinction is made between:
a) Metal lubricating soaps (calcium, Al, Ba, Li, Na and complex lubricating greases, etc.) composed of fatty acids and lyes of metal soaps (thickeners and swelling agents) as well as lubricating oils. Metal soaps, lubricating oils and the manufacturing process determine the structure, consistency, suitability for use and application.
b) Soap-free lubricating greases with inorganic gel-forming agents (gelatinous silica, silica gel, bentonite, etc.) or organic thickening agents (polyethylene, polypropylene, polyurea, etc.) and lubricating oils.
c) Synthetic lubricating greases which consist of organic and inorganic thickening agents and synthetic oils (ester, silicone, polyglycol and polyphenylether oils, etc.).
Precise lubricating instructions with maintenance instructions, designation of lubricating points, the type and quantity of lubricants, intervals, etc. for the individual machine types and their units.
MARINE DIESEL ENGINE OILS
Various marine diesel engine oils are used for ships that sail on the high seas. The type depends on the engine type, engine speed, operation and fuel:
a) Engine oils in accordance with API CD can be used for stationary diesel engines and fast-running trunk piston diesel engines and for operation with diesel fuel.
b) Marine diesel engine oils with very good detergent-dispersant characteristics and good thermal and oxidative resistance should be used for trunk piston diesel engines that run at medium speeds and use residual heavy oil for fuel.
c) Only highly alkaline marine diesel engine oils with very good dispersive and neutralizing properties should be used to lubricate cylinders on crosshead engines that also use residual heavy oil for fuel.
Dialkylzinc dithiophosphates; metal phenates; organic nitrogen and sulphur compounds, amines, benzotriazoles, derivates, certain soaps, etc. The effect is based on the formation of surface films so that metal surfaces cannot induce oil oxidation catalytically.
Metals and their compounds react with fatty acids and form metallic soaps; these are used as EP additives in lubricating oils and as thickening agents in lubricating greases.
Collective term for cutting oils, rolling oils, drawing oils and drilling oils, both water-miscible and non-water-miscible; standard term is coolant. Their main tasks depend on the application: lubrication, cooling, transportation of swarf, corrosion protection, etc. (See coolants.)
METHANE – CH4
First molecule of the paraffinic (alkane) family of hydrocarbons; main component of natural gas; also, contained in refinery gas, coal gas, etc.
Specifications of the US military with minimum requirements for the operating supplies they purchase; some engine and machine manufacturers specify the same minimum requirements,
i.e. in accordance with MIL specifications; compliance with minimum requirements is considered to be a quality standard.
Mineral oils and mineral oil products are liquid distillation and refinery products obtained from petroleum, a mineral-based raw material, and which primarily consist of mixtures of saturated and possibly very small amounts of unsaturated hydrocarbons.
Is a friction situation where boundary friction and viscous friction occur together/
in sequence. Surface roughness (roughness points) are sometimes separated but sometimes contact is made so that wear occurs.
MOLYBDENUM DISULPHIDE (MOS2)
This is a solid lubricant with a layer lattice structure. If it is properly worked into the metal surface, this solid body with a lamellar structure can reduce the coefficient of friction of the surface for a period of time. It is often use as an additive mixed in with lubricating oils, lubricating greases, compounds, etc.
a) Moulds made of wood, metal or similar material for the manufacture of concrete, ceramics, pantiles, etc. are lubricated with thin oils or emulsions for effective release of the moulded parts.
b) Core oils for mixing with moulding sand.
These are industrial lubricants which use special additives to meet the requirements of various machine tools units. They can therefore be used as gear oils, slide oils, cutting oils, etc.
Multi-Grade Engine and Gear Oils
These are lubricating oils which are intended for use in vehicles all the year round thanks to their very good viscosity temperature characteristics. They cover several SAE classes, for multi-grade engine oils:
5W-30, 10W-30, 5W-40, 15W-50, etc.,
VI approx. 130 to 170.
For multi-grade gear oils: 75W-90, 80W-90, 85W-140, etc.,
VI approx. 115 to 170.
OCTANE NUMBER (ON)
This is a dimension value for the anti-knock properties of petrol; it describes the behaviour of fuel during combustion in the engine. For the combustion process to operate normally, it is essential for the fuel to have adequate anti-knock properties - see anti-knock resistance. Reference fuels are: n-heptane with ON = 0 and Iso octane with ON = 100, determined in DIN 51 756 P 1 to P 6.
OIL COAL OR OIL COKE
Hard deposits like coal or coke in cylinders and piston ring grooves of internal combustion engines, etc. Occurs in recirculating oils if the oil has aged, and also as a result of the ingress of contaminants and thermal loading.
It is possible that small amounts of oil may separate from lubricating greases if it is stored for a long time or if it operates at higher operating temperatures. This is normal and of no significance. However, it is not acceptable for larger amounts of oil to separate out (what is termed bleeding). DIN 51 817 sets out conditions of oil separation under static conditions.
A distinction is made between the source, manufacture and the chemical structure:
a) Animal and vegetable oils: these are esters or fatty acids
b) Mineral oils, which - depending on their structure - are composed of paraffins (alkanes)
naphthenes (cycloalkanes) or aromats
c) Synthetic oils, such as silicone oils, polyglycols, ester compounds, etc.
Organic oxygen and/or sulphur compounds which are found in dissolved form in petroleum products; generally, have strong dyeing effect; oil resins are absorbed in silica gel or bleaching earth.
Outboard Marine Corporation; manufacturer of spark-ignition engines for 2- and 4-stroke outboard motors, chain saws, etc.; the OMC specifications specifically set out requirements for two-stroke engine oils.
Organisation of the Petroleum Exporting Countries.
Oxidation is a combustion process; oxygen is attached to certain elements or molecules. Thickening, varnishing, polymers, corrosive-acting radicals, etc. occur in the case of hydrocarbons.
(Antioxidants – AO) dialkylzinc dithiophosphates; compounds of nitrogen, phosphorus and sulphur (amines, phenoles in combination with zinc, tin, barium, calcium, etc.). They prevent or control the oxidation of oil and the formation of sludge, varnishing and corrosive compounds. They thus limit or retard the increase in viscosity of the lubricating oil.
Outdated designation for paraffin liquid, white oils and light mineral oils – see white oil, vaseline.
PARAFFIN SEPARATION (START OF PARAFFIN SEPARATION)
Start of paraffin separation under specified test conditions for diesel fuels indicated in °C; relevant measuring methods. limit of filterability (CFPP), cloud point (CP).
Gaseous, fluid and solid chain, saturated hydrocarbon compounds; a distinction is made between normal paraffins with a chain structure and iso(i) paraffins with a branched structure.
As a result of low sliding speed or excessive pressure, the sliding surfaces are not fully separated; there is both hydrodynamic lubrication and contact between the sliding surfaces (mixed friction) – see friction.
Is a dimension for consistency (solidity or fluidity) of a substance. In the case of lubricating greases, it is the amount by which a cone with specified dimensions penetrates vertically into the specimen to be examined under specified conditions. DIN ISO 2137, DIN 51 804 P 2 – see consistency, unworked penetration and worked penetration.
Device to determine penetration.
Undesirable chemical compounds, organic and inorganic, which favour the formation of resins through oxidation and polymerisation.
Consists of a chain and cyclic hydrocarbon mixture with a boiling range of approx. 30 to 215°C to operate petrol engines; leaded petrol: DIN 51 600; unleaded petrol: DIN 51 607, EN 228 - also see benzin.
In porous rocks below the surface of the earth, hydrocarbon mixtures made of animal and vegetable greases produced by temperature, pressure and catalytic mechanisms of action, contains negligible amounts of oxygen, sulphur, nitrogen and metals; a distinction is made between paraffin-base, naphthene-base and mix-base petroleum oils.
Hydrocarbon fraction from petroleum, the boiling range is between 130 and 280°C, hazard class A II or A III depending on the fraction. Used as oil for illumination, burning or as a solvent, also called kerosene: DIN 51 636.
Dimension for hydrogen (H) ionic concentration in an aqueous solution for an acidic and alkaline reaction: pH value = 7: neutral; pH > 7: alkaline; pH < 7: acidic. Important for checking coolants mixed with water. pH paper or electric measuring devices are used for measurement. DIN 51 369.
Pipeline through which petroleum, crude oil, mineral oil products and other liquid media or gases are transported.
Small cavities that appear on the surface of gear teeth as a result of material fatigue; in the rolling circle area, small cracks form, which later develop into small recesses and holes in the surface.
From the Greek for "wandering thing"; all animal and plant microorganisms freely suspended in water, which are the main constituents of sapropel and later lead to the formation of reserves of petroleum.
Catalytic reforming of straight-run benzin using catalytic converters containing platinum.
A unit of dynamic viscosity; can be calculated from the measured cinematic viscosity (Stokes) by multiplication with the density of the fluid to be tested at a certain test temperature (see viscosity).
These are synthetic hydrocarbons (especially Iso paraffins with short main and long side chains), which are produced from paraffin slack wax by means of hydro cracking processes using a certain catalytic technology (polymerisation and copolymerisation of low olefins).
Combination of unsaturated hydrocarbon molecules to form a large molecule (thickening) in the presence of catalysts and heat (manufacturing process for synthetic lubricating oils).
Is the temperature at which cooling oil just stops flowing under specified conditions. The pour point only provides limited information on the low-temperature flow characteristics of an oil in a certain machine. To determine the pour point: DIN ISO 3016
POUR POINT IMPROVER
Active ingredients which, when mineral oils (primarily paraffin-based oils) cool down, initially prevent the clumping of the paraffin crystals that are forming and thus improve fluidity when cold.
POUR POINT MODIFIER
Polymethacrylates, alkyl-phenoles, naphthalene with chlorinated paraffins, propylene copolymers, etc. The effect is based on preventing the paraffin crystals from clumping together or becoming waxy, thus giving better fluidity. The oil only solidifies at lower temperatures – also see pour point modifiers.
Unit of measure: parts per million.
Engine oil with active ingredients (oxidation and corrosion inhibitors).
Imidazoles, amidoacetate, etc. During use coolants mixed with water (e.g. oil-in-water emulsions) can provide good nutrients for fungus, yeasts and bacteria, which cause various problems (corrosion, odour, etc.). The purpose of preservative agents is to prevent the relevant germs from spreading. It is important to check the number of germs on a regular basis.
These are used to preserve wood, e.g. to impregnate railroad sleepers and to soak porous materials such as insulating materials, paper and leather.
Gaseous hydrocarbons at normal temperature C3H8: DIN 51 622.
Metal-processing oil for protecting tools and workpieces when punching metal or to make compounds that need to be shaped such as porcelain, etc. supple.
A container whose volume is precisely known to determine density p: DIN 51 757.
Distillate enhanced by chemical and/or physical procedures.
Carbonisation test for lubricating oils: DIN ISO 4262; EN 8.
Reclaimed used oil is the product of reprocessed used oils. This involves centrifugal processing and filtering of sludge, water and mechanical contaminants. MOTOREX never uses reclaimed oils.
REDWOOD SECONDS (R”)
A conventional measure for viscosity commonly used in England, Redwood viscometer.
Hydrocarbons still contain compounds with sulphur, oxygen, nitrogen and other contaminants after distillation and vacuum distillation; these are separated from the hydrocarbons during subsequent refining as a result of chemical-physical processes using solvents or acids, thus improving quality considerably.
Conversion of hydrocarbons (benzin) with a low octane number into benzin with a high octane number.
a) Thermal reforming: Long-chain paraffin hydrocarbons are converted into aromatics and olefins.
b) Catalytic reforming: Long-chain paraffin hydrocarbons are converted into isoparaffins and aromatics.
Specifies the deflection of a beam of light of a certain wavelength as it passes through a material, e.g. to identify oils. Provides information on the molecular composition.
Device to determine by visual means (calculate the light beam) the oil content of a water-mixed coolant (emulsion).
Non-compounded lubricating oil, in some cases high-quality refined products but without active
In the context of distilling or cracking, the liquid parts that have not evaporated, axle oil, bright stocks, etc
Ageing of mineral oil products through the formation of highly polymerised condensation products.
Sticking and formation of residues in piston ring groves; piston rings stick.
ROLLER-CONTACT BEARING GREASES
Lubrication for roller-contact bearings, generally lubricating grease containing lithium soap or, in some cases, sodium soap lubricating grease as well. Calcium soap lubricating grease is suitable for use when subject to exposure to considerable amounts of water.
Research Octane Number = Dimension value for the anti-knock properties of petrol, e.g. 95, 98 or 100 RON.
Grease to preserve rope made of all kinds of natural fibres and keep it supple. Rope grease is often rapidly biodegradable.
Corrosion produced by the simultaneous effect of oxygen and moisture on the surface of iron or steel (hydrated ferric oxide).
See corrosion-protecting oils and greases.
Society of Automotive Engineers. International society of over 83,000 engineers from 97 countries, which exchange know-how in the fields of automotive engineering, aerospace, engines, commercial vehicles, production, fuels and materials.
More at www.sae.org/about/
SELECTIVE SOLVENT REFINING
Refining using solvents (duo-sol, Edeleanu, furfurol processes, etc.); undesirable hydrocarbon compounds are released from the individual hydrocarbon types and separated.
Is the temperature at which a flammable substance will ignite without external ignition, depending on the conditions (temperature, pressure, etc.) and the oxygen content of the surrounding air.
SEWING MACHINE OILS
Very thin-bodied technical white oil, 7 to 12 mm2/s at 40°C, often contains solid additives.
Viscosity index improvers (polymers soluble in oil) are added to lubricating oils, hydraulic oils, etc. to improve the viscosity-temperature characteristics. Some of these polymer molecules, which have linear, lattice or net structures, have a huge molecular structure in the high-temperature range (macro molecules) and then change or break their molecular structure when exposed to shear forces, as occur in gears or hydraulic systems. Here there is a loss of viscosity to a greater or lesser extent.
Silicone oxide compounds, which exist in forms that range from viscous to solid. The various viscous silicones are generally colourless oils with very good viscosity temperature properties. They are used as additives, synthetic oils, hydraulic oils, insulating agents, etc. in the mineral oil industry. Solid silcones are very resistant to temperature.
Ageing of mineral oils. The influence of air and water may cause mineral products to form oxidation substances and polymerisation may occur; if this problem is pronounced, these oxidation products are no longer dispersed in oil so they solidify and form sludge.
SODIUM COMPLEX SOAP LUBRICATING GREASE
Has good lubricating characteristics, with good adhesion and especially low oil separation, thus making it particularly suitable for fast-running bearings. It is, however, very sensitive to water.
SODIUM LUBRICATING GREASE
Lubricating grease made of sodium soap and mineral oils; can be used up to operating temperatures of 120°C. Sodium lubricating greases are emulsfiable and must not be used at wet lubricating points. They are very suitable for lubricating gears and as fluid gear greases in NLGI classes 0,00,000.
Is generally only used and required for lubricating tasks under extreme conditions (e.g. for operation in mixed friction areas). The best known are graphite, molybdenum disulphide and plastics such as polytetrafluoroethylene, etc. These are applied directly in powder form, in suspensions, pastes, metallic films, paints and plastics.
Solvent-neutral oils, solvent raffinates, mineral oils refined with solvents.
Pure amorphous carbon, which is produced by incomplete combustion of fuels containing carbon.shear stability: DIN 51 382; CEC L-14-A-88; L-25-A-78; L-37-T-85; L-45-T-92.
Are used as dielectric materials during spark-erosion machine operations on what are generally very hard metals. They must provide good insulation, cool the tool and workpiece and they should be readily ionisable. Some of the points that good products feature, are: very little volatility, high flash point, oxidation stability, non-aggressive to the skin and seals, chemically neutral, highly refined, low in aromatics. Viscosity is approx. 2 to 4.5 mm2/s at 40°C.
Specifications for lubricants and fuels in which physical characteristics, chemical characteristics and test methods are specified.
Radiation energies of various wavelengths, e.g. infrared rays, cause hydrocarbon molecules to reflect radiation which varies according to the molecule and thus allow the structure of the molecule or additives or metal abrasives to be identified.
Thin-bodied lubricating oil for lubricating spindles in textile machines; viscosity around 10 to 80 mm2/s at 20°C. Also, lubricants to lubricate and cool electrically powered spindles in machine tools, etc.
Lubricating greases to lubricate leaf springs, generally containing MoS2 or graphite.
Active ingredients, inhibitors which protect the medium from ageing.
Additives (friction-modifying active ingredients) added to gear oils and other lubricants in order to prevent stick-slip effects – e.g. for slideways on machine tools – at very low speeds.
1 St (Stokes) = 1 cm2/s = 100 cSt = 100 mm2/s
Unit to measure cinematic viscosity.
SUPER TRACTOR OIL UNIVERSAL - STOU
Hydraulic oil for engines and gearboxes for universal application in as many engines, machines, devices and units as possible, in particular with wet brakes and clutches in agriculture and the construction industry. To streamline types and prevent different lubricants from mixing when different items of equipment are connected together.
These lubricants are developed for special technical applications and special requirements. Nowadays they are specified for high-performance engines and aggregates and also for special purposes, for instance requirements such as fire resistance, high-temperature stability, low-temperature performance, resistance to radioactive radiation, volatility loss, resistance to oxidation (complying with service life), high-pressure stability, viscosity temperature characteristics, etc.
The response of additives for the various synthetic lubricants is very different and results in the development of new additive combinations, which in some cases can only be used for certain synthetic lubricants. The following synthetic lubricants are used: Polyalkylene glycols, synthetic hydrocarbons (e.g. polyalphaolefins, dialkylbenzole, polyisobutylene), dicarbon acid and polyalcohol ester, phosphoric acid ester, silicone, polyphenyl ether, fluorocarbons, etc.
TACKY LUBRICATING OILS
Lubricating oils with adhesion improvers, tacky viscous, often bituminous, highly viscous lubricants, which are also diluted before use.
THINNING OF LUBRICATING OIL
This occurs in spark-ignition engines if, when the engine is cold, fuel condenses on the cylinder and is then mixed with the lubricating oil through the pumping action at the piston rings. The same phenomenon may occur with fuels with a high final boiling point. When benzin thins lubricating oil in the engine oil, viscosity is reduced and thus jeopardizes lubrication. Testing in accordance with DIN: 51 565.
Non-water-miscible lubricants (metalworking oils) for cutting metal operations. The task of these oils is to lubricate, dissipate heat and remove swarf.
Grease testing machine to determine the high-pressure characteristics of lubricating oils (wear tester). A square test plate is pressed against a moving shaft with the anti-friction bearing ring fitted; to ascertain the loading and appearance of the test specimen.
Tribology covers scientific research and technical applications of friction, wear and lubrication, taking account of design, materials science, regulations imposed by the authorities, etc. Tribo technology also deals with the retention of the value of machines and tools, simplification of lubrication application, minimisation of energy losses plus environmental demands, cost-optimised production and targeted maintenance schedules.
TWO-STROKE ENGINE OILS
When lubricating two-stroke spark-ignition engines, a distinction is made between the following two-stroke engine oils according to the engine type, use, lubrication system, miscibility, mixing ratio, corrosion protection, cleaning effect, biological degradability, etc.:
a) Self-mixing (pre-diluted)
b) Not self-mixing (not pre-diluted) for automatic fresh oil (fresh oil lubrication)
c) Outboard motor oils
The two-stroke oils are classified into three API service categories (American Petroleum Institute): TA, TB, TC for mopeds, scooters, motorcycles and agricultural equipment. There are also the JASO specifications (Japan Automobile Standards Organisation) FA, FB and FC for engine oils with a low sulphate ash content for air-cooled two-stroke engines.
This type of distillation is used for the manufacture of lubricating oils, because distillation at normal pressure (atmospheric distillation) would break (crack) the larger hydrocarbon molecules – see distillat
Natural or artificial mixtures of solid and liquid hydrocarbons made of petroleum, free of odour and taste. Natural vaseline is made of petrolatum by means of refining.
Sheet for measuring and recording the viscosity obtained for mixtures.
Device for determining the viscosity of fluids. A distinction is made between: capillary, rotation, falling-ball and efflux viscometers.
Viscosity is the characteristic of a fluid to offer resistance to the interacting laminar movement (deformation) of two adjacent layers (internal friction, shear stress): DIN 1342, DIN 51 550, DIN ISO 3104.
See SAE classes and ISO viscosity classification.
VISCOSITY INDEX (VI)
It is a calculated figure on a conventional scale which describes how the viscosity of a mineral oil or synthetic oil product changes with the temperature. A higher viscosity index indicates a smaller change in viscosity with temperature than a lower viscosity index. Calculation of the VI from the cinematic viscosity: DIN ISO 2909, ASTM D 2270.
VISCOSITY INDEX IMPROVER
Active ingredients (viscosity improver, polymers), which - when dissolved in the mineral oil - improves the viscosity temperature characteristics, i.e. they reduce the temperature dependency of viscosity; at low temperatures, they improve the flow properties and at high temperatures they achieve a higher viscosity than would be the case without VI improvers. VI improvers are important constituents of multi-grade lubricating oils. The most important viscosity index improver groups are: Polymethacrylates (PMA), olefin copolymers (OCP), polyisobuthylene (PIB) and styrene-butadiene copolymers (SCB) or styrene-isoprene copolymers (SIC).
VISCOSITY TEMPERATURE CHARACTERISTICS (VT)
The VT of a fluid is how the viscosity alters as a function of the change in temperature – see viscosity index.
Exists when rubbing surfaces on top of each other are completely separated by a lubricant so that there is no direct contact. No wear occurs. The viscosity, temperature, shear rate and the pressure properties of the lubricant determine the viscous friction.
VOLATILITY LOSS (NOACK)
Volatility loss of lubricating oil at higher temperatures (up to 350°C); it is particularly important for engine and cylinder lubrication. At the high temperatures that occur, a high volatility loss may be equivalent to a higher oil consumption and may lead to a change in the characteristics of the oil: DIN 51 581 (Noack Test).